Supramolecular polymerization controlled through kinetic trapping

Image credit: Wiley

摘要

The kinetics of supramolecular polymerization with a rigid host and a flexible guest monomer can be controlled through the introduction of a pH-responsive competitive guest (green rod; blue pathway). This polymerization system can be kinetically trapped by tuning pH at different stages, and supramolecular polymers with different molecular weights can be obtained. Red pathway: uncontrolled.

论文
Angew. Chem. Int. Ed., 2017, 56, 16575-16578
黄泽寰
黄泽寰
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父亲,丈夫,儿子以及超分子生物材料研究者